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九的原子Deltahedral Zintl离子锗和他们的官能合成有机基团
JoVE Journal
Biology
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JoVE Journal Biology
Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
DOI:

08:15 min

February 11, 2012

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Chapters

  • 00:05Title
  • 01:15Niobium Tubes: K4Ge9
  • 03:14Glass-Blowing Fused Silica/Quartz Jacket
  • 05:16Reaction to [H2C=CH-Ge9-CH=CH2]2- Clusters
  • 06:12Cystals of Ge9-divinyl Ions
  • 07:11Functionalized Deltahedral Zintl Clusters
  • 07:34Conclusion

Summary

Automatic Translation

我们提出的K高温金属间化合物的前体的合成<sub> 4</sub> GE<sub> 9</sub>,他们在解散乙二胺形成GE<sub> 9</sub<sup> 4 -</sup> deltahedral Zintl离子,炔集群的反应形成有机Zintl离子。后者的特点是通过电质谱解决方案,并通过单晶X-射线衍射固态。

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